Xu W, Yu S S, Zhang H, Duan H B
Department of Chemistry, Huangshan University Huangshan 245041 P. R. China.
School of Environmental Science, Nanjing Xiaozhuang University Nanjing, 211171 P. R. China
RSC Adv. 2019 May 23;9(28):16183-16186. doi: 10.1039/c9ra03032h. eCollection 2019 May 20.
A three-dimensional metal-organic framework compound [NH(CH)][Zn(bpdc)]·3DMF (1) shows two step dielectric relaxation and its guest-free framework (1') possesses an ultra-low value of 1.80 (at 100 kHz, it is the lowest value for MOFs reported to date) over a wide temperature range and high thermal stability.
一种三维金属有机骨架化合物[NH(CH)][Zn(bpdc)]·3DMF (1)表现出两步介电弛豫,其无客体骨架(1')在很宽的温度范围内具有1.80的超低值(在100 kHz时,这是迄今为止报道的金属有机骨架材料的最低值)以及高热稳定性。