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一种用于无客体超低介电材料的三维金属有机框架。

A three-dimensional metal-organic framework for a guest-free ultra-low dielectric material.

作者信息

Xu W, Yu S S, Zhang H, Duan H B

机构信息

Department of Chemistry, Huangshan University Huangshan 245041 P. R. China.

School of Environmental Science, Nanjing Xiaozhuang University Nanjing, 211171 P. R. China

出版信息

RSC Adv. 2019 May 23;9(28):16183-16186. doi: 10.1039/c9ra03032h. eCollection 2019 May 20.

DOI:10.1039/c9ra03032h
PMID:35521392
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9064416/
Abstract

A three-dimensional metal-organic framework compound [NH(CH)][Zn(bpdc)]·3DMF (1) shows two step dielectric relaxation and its guest-free framework (1') possesses an ultra-low value of 1.80 (at 100 kHz, it is the lowest value for MOFs reported to date) over a wide temperature range and high thermal stability.

摘要

一种三维金属有机骨架化合物[NH(CH)][Zn(bpdc)]·3DMF (1)表现出两步介电弛豫，其无客体骨架(1')在很宽的温度范围内具有1.80的超低值(在100 kHz时，这是迄今为止报道的金属有机骨架材料的最低值)以及高热稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddb5/9064416/66694f3c49b9/c9ra03032h-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddb5/9064416/2c0ebc5c036e/c9ra03032h-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddb5/9064416/770cff397d89/c9ra03032h-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddb5/9064416/66694f3c49b9/c9ra03032h-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddb5/9064416/2c0ebc5c036e/c9ra03032h-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddb5/9064416/770cff397d89/c9ra03032h-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddb5/9064416/66694f3c49b9/c9ra03032h-f3.jpg

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