State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, PR China; College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, PR China.
Ultrason Sonochem. 2014 Jan;21(1):129-35. doi: 10.1016/j.ultsonch.2013.07.013. Epub 2013 Aug 7.
An easy, one-step synthesis of Cu2O-reduced graphene composites (Cu2O-rGO) was developed using a simple sonochemical route without any surfactants or templates. The morphology and structure of the Cu2O-rGO composites were characterised using techniques such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). The results indicated that the Cu2O sphere is approximately 200 nm in diameter and composed of small Cu2O particles approximately 20 nm in diameter. The morphology and composition of the Cu2O-rGO composites could be well controlled by simply changing the mole ratio of the reactants under ultrasonic irradiation. The Cu2O-rGO composites displayed better photocatalytic performance for the degradation of methyl orange (MO) than pure Cu2O spheres, which may have potential applications in water treatment, sensors, and energy storage.
采用简单的超声化学法,无需使用表面活性剂或模板,制备了 Cu2O 还原氧化石墨烯复合材料(Cu2O-rGO)。采用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X 射线衍射(XRD)、傅里叶变换红外(FT-IR)光谱、拉曼光谱和 X 射线光电子能谱(XPS)等技术对 Cu2O-rGO 复合材料的形貌和结构进行了表征。结果表明,Cu2O 球的直径约为 200nm,由直径约 20nm 的小 Cu2O 颗粒组成。通过在超声辐射下简单改变反应物的摩尔比,可以很好地控制 Cu2O-rGO 复合材料的形貌和组成。Cu2O-rGO 复合材料对甲基橙(MO)的光催化降解性能优于纯 Cu2O 球体,在水处理、传感器和储能方面具有潜在的应用价值。