IBM T. J. Watson Research Center , Yorktown Heights, New York 10598, United States.
ACS Nano. 2013 Sep 24;7(9):8303-8. doi: 10.1021/nn403935v. Epub 2013 Sep 5.
So far, realization of reproducible n-type carbon nanotube (CNT) transistors suitable for integrated digital applications has been a difficult task. In this work, hundreds of n-type CNT transistors from three different low work function metals-erbium, lanthanum, and yttrium-are studied and benchmarked against p-type devices with palladium contacts. The crucial role of metal type and deposition conditions is elucidated with respect to overall yield and performance of the n-type devices. It is found that high oxidation rates and sensitivity to deposition conditions are the major causes for the lower yield and large variation in performance of n-type CNT devices with low work function metal contacts. Considerable improvement in device yield is attained using erbium contacts evaporated at high deposition rates. Furthermore, the air-stability of our n-type transistors is studied in light of the extreme sensitivity of these metals to oxidation.
到目前为止,实现适用于集成数字应用的可重复的 n 型碳纳米管 (CNT) 晶体管一直是一项艰巨的任务。在这项工作中,研究了来自三种不同低功函数金属-铒、镧和钇的数百个 n 型 CNT 晶体管,并将其与具有钯接触的 p 型器件进行了基准测试。对于 n 型器件的整体产量和性能,金属类型和沉积条件的关键作用得到了阐明。研究发现,高氧化速率和对沉积条件的敏感性是导致具有低功函数金属接触的 n 型 CNT 器件产量较低和性能变化较大的主要原因。使用高沉积速率蒸发的铒接触可以显著提高器件的产量。此外,根据这些金属对氧化的极端敏感性,研究了我们的 n 型晶体管的空气稳定性。