School of Environmental Sciences, Jawaharlal Nehru University, New Delhi, India.
Environ Sci Pollut Res Int. 2014 Feb;21(3):2240-2248. doi: 10.1007/s11356-013-2150-7. Epub 2013 Sep 18.
The present work investigated the levels of total volatile organic compounds (TVOC) and benzene, toluene, ethylbenzene, m/p-xylene, and o-xylene (BTEX) in different microenvironments in the library of Jawaharlal Nehru University in summer and winter during 2011-2012. Carcinogenic and non-carcinogenic health risks due to organic compounds were also evaluated using US Environmental Protection Agency (USEPA) conventional approaches. Real-time monitoring was done for TVOC using a data-logging photo-ionization detector. For BTEX measurements, the National Institute for Occupational Safety and Health (NIOSH) standard method which consists of active sampling of air through activated charcoal, followed by analysis with gas chromatography, was performed. Simultaneously, outdoor measurements for TVOC and BTEX were carried out. Indoor concentrations of TVOC and BTEX (except benzene) were higher as compared to the outdoor for both seasons. Toluene and m/p-xylene were the most abundant organic contaminant observed in this study. Indoor to outdoor (I/O) ratios of BTEX compounds were generally greater than unity and ranged from 0.2 to 8.7 and 0.2 to 4.3 in winter and summer, respectively. Statistical analysis and I/O ratios showed that the dominant pollution sources mainly came from indoors. The observed mean concentrations of TVOC lie within the second group of the Molhave criteria of indoor air quality, indicating a multifactorial exposure range. The estimated lifetime cancer risk (LCR) due to benzene in this study exceeded the value of 1 × 10(-6) recommended by USEPA, and the hazard quotient (HQ) of non-cancer risk came under an acceptable range.
本研究调查了 2011-2012 年间夏季和冬季贾瓦哈拉尔尼赫鲁大学图书馆不同微环境中总挥发性有机化合物(TVOC)以及苯、甲苯、乙苯、间/对二甲苯和邻二甲苯(BTEX)的浓度。还使用美国环保署(USEPA)的常规方法评估了有机化合物造成的致癌和非致癌健康风险。使用带有数据记录功能的光离子化检测仪实时监测 TVOC。对于 BTEX 的测量,采用了美国国家职业安全与健康研究所(NIOSH)的标准方法,该方法包括通过活性炭进行空气的主动采样,然后用气相色谱法进行分析。同时,还进行了 TVOC 和 BTEX 的室外测量。对于两个季节,室内的 TVOC 和 BTEX(除苯外)浓度均高于室外。本研究中,甲苯和间/对二甲苯是最丰富的有机污染物。BTEX 化合物的室内外(I/O)比值通常大于 1,范围分别为冬季 0.2-8.7 和夏季 0.2-4.3。统计分析和 I/O 比值表明,主要污染源主要来自室内。观察到的 TVOC 平均浓度处于室内空气质量 Molhave 标准的第二组内,表明存在多因素暴露范围。本研究中由于苯造成的预期终生癌症风险(LCR)超过了 USEPA 建议的 1×10(-6)值,非癌症风险的危害商(HQ)处于可接受范围内。