Research and Development, Tofwerk AG, Uttigenstrasse 22, 3600 Thun, Switzerland.
J Mass Spectrom. 2013 Sep;48(9):998-1004. doi: 10.1002/jms.3248.
A number of possible ultraviolet MALDI ionization mechanisms based on different fundamental phenomena have been proposed. Recently, it has been argued, based on 'temperature'-selected spectra, that photoionization models should be rejected in favor of thermal ones. Here, one non-thermal photoionization model, the coupled photophysical and chemical dynamics model, is shown to be fully consistent with the data.
已经提出了一些基于不同基本现象的可能的紫外线 MALDI 电离机制。最近，有人提出，基于“温度”选择的光谱，应该拒绝光致电离模型，转而支持热模型。在这里，一个非热光致电离模型，即耦合光物理和化学动力学模型，被证明与数据完全一致。
