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一种通用的[Cu(X)(NHC)]（NHC = N-杂环卡宾，X = Cl、Br、I）配合物的合成路线。

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes.

机构信息

EaStCHEM School of Chemistry, University of St Andrews, St Andrews, KY16 9ST, UK.

出版信息

Chem Commun (Camb). 2013 Nov 18;49(89):10483-5. doi: 10.1039/c3cc45488f.

DOI:10.1039/c3cc45488f
PMID:24087835
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4155829/
Abstract

A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air.

摘要

本文报道了一种一锅法合成[Cu(X)(NHC)]（X = Cl，Br，I）的方法。该反应适用于广泛的饱和和不饱和 NHC 配体，可规模化进行，并在空气中使用工业级溶剂在温和条件下进行。

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