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钯催化的C(sp(2))-H键交叉脱氢官能团化反应

Palladium-catalyzed cross-dehydrogenative functionalization of C(sp(2))-H Bonds.

作者信息

Wu Yinuo, Wang Jun, Mao Fei, Kwong Fuk Yee

机构信息

State Key Laboratory of Chirosciences, Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong (Hong Kong), Fax: (+852) 2364-9932; School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou (China).

出版信息

Chem Asian J. 2014 Jan;9(1):26-47. doi: 10.1002/asia.201300990. Epub 2013 Oct 2.

Abstract

The catalytic cross-dehydrogenative coupling (CDC) reaction has received intense attention in recent years. The attractive feature of this coupling process is the formation of a C-C bond from two C-H moieties under oxidative conditions. In this Focus Review, recent advances in the palladium-catalyzed CDC reactions of C(sp(2) )-H bond are summarized, with a focus on the period from 2011 to early 2013.

摘要

近年来,催化交叉脱氢偶联(CDC)反应受到了广泛关注。该偶联过程的一个吸引人的特点是在氧化条件下由两个C-H部分形成C-C键。在这篇重点综述中,总结了钯催化的C(sp(2) )-H键CDC反应的最新进展,重点关注2011年至2013年初这一时期。

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