Department of Science and Mathematics, Trevecca Nazarene College, 37203, Nashville, TN, USA.
Environ Monit Assess. 1987 Jul;9(1):1-11. doi: 10.1007/BF00394211.
Solubilities of several hydrophobic organic substances (paradichlorobenzene, endrin, naphthalene, and dibutyl phthalate) in aqueous solutions containing up to 0.10 mole fraction of common alcohols and ketones, were measured by gas chromatography. The solubilities are significantly increased by the alcohols and ketones. The results are interpreted in terms of the association of n molecules of alcohol or ketone with each hydrophobic organic molecule. Values of n and the equilibrium constant for this association are reported for each hydrophobic organic-alcohol and organic-ketone combination. The implications of these results for the disposal of toxic wastes by landfilling is discussed.
采用气相色谱法测定了高达 0.10 摩尔分数的常见醇和酮水溶液中几种疏水性有机物质（对二氯苯、艾氏剂、萘和邻苯二甲酸二丁酯）的溶解度。醇和酮显著增加了溶解度。这些结果根据 n 个醇或酮分子与每个疏水分子的缔合来解释。报告了每个疏水性有机-醇和有机-酮组合的 n 值和该缔合的平衡常数。讨论了这些结果对通过填埋处理有毒废物的影响。
