Heravi Majid M, Hajiabbasi Parvin
Department of Chemistry, School of Science, Alzahra University, Vanak, Tehran, Iran,
Mol Divers. 2014 May;18(2):411-39. doi: 10.1007/s11030-013-9494-2. Epub 2013 Dec 31.
In this review, we try to highlight the recently reported stereoselective Michael conjugate additions of heteroatom nucleophiles to electron-deficient alkenes. The topic is divided based on the nature of the nucleophile employed (nitrogen-, oxygen-, sulfur-, or phosphorus-centered) and then subdivided to distinguish between catalyst-controlled and substrate/reagent-controlled methods which is necessary to achieve asymmetric synthesis.
在本综述中，我们试图突出近期报道的杂原子亲核试剂对缺电子烯烃的立体选择性迈克尔共轭加成反应。该主题根据所使用亲核试剂的性质（以氮、氧、硫或磷为中心）进行划分，然后再细分以区分催化剂控制法和底物/试剂控制法，这对于实现不对称合成是必要的。
