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钙钛矿太阳能电池的一般工作原理。

General working principles of CH3NH3PbX3 perovskite solar cells.

机构信息

Photovoltaics and Optoelectronic Devices Group, Departament de Fisica, Universitat Jaume I , 12071 Castello, Spain.

出版信息

Nano Lett. 2014 Feb 12;14(2):888-93. doi: 10.1021/nl404252e. Epub 2014 Jan 10.

Abstract

Organometal halide perovskite-based solar cells have recently realized large conversion efficiency over 15% showing great promise for a new large scale cost-competitive photovoltaic technology. Using impedance spectroscopy measurements we are able to separate the physical parameters of carrier transport and recombination in working devices of the two principal morphologies and compositions of perovskite solar cells, viz. compact thin films of CH3NH3PbI(3-x)Clx and CH3NH3PbI3 infiltrated on nanostructured TiO2. The results show nearly identical spectral characteristics indicating a unique photovoltaic operating mechanism that provides long diffusion lengths (1 μm). Carrier conductivity in both devices is closely matched, so that the most significant differences in performance are attributed to recombination rates. These results highlight the central role of the CH3NH3PbX3 semiconductor absorber in carrier collection and provide a new tool for improved optimization of perovskite solar cells. We report for the first time a measurement of the diffusion length in a nanostructured perovskite solar cell.

摘要

基于金属有机卤化物钙钛矿的太阳能电池最近实现了超过 15%的高效率,为新的大规模、具有成本竞争力的光伏技术带来了巨大的希望。通过阻抗谱测量,我们能够分离出两种主要形态和组成的钙钛矿太阳能电池(即 CH3NH3PbI(3-x)Clx 致密薄膜和纳米结构 TiO2 上渗透的 CH3NH3PbI3)工作器件中载流子输运和复合的物理参数。结果表明,光谱特性几乎完全相同,表明存在独特的光伏工作机制,提供了长扩散长度(1 μm)。两种器件中的载流子电导率非常匹配,因此性能的最大差异归因于复合速率。这些结果突出了 CH3NH3PbX3 半导体吸收体在载流子收集方面的核心作用,并为改进钙钛矿太阳能电池的优化提供了新工具。我们首次报道了在纳米结构钙钛矿太阳能电池中测量扩散长度。

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