文献检索文档翻译深度研究
Suppr Zotero 插件Zotero 插件
邀请有礼套餐&价格历史记录

新学期,新优惠

限时优惠:9月1日-9月22日

30天高级会员仅需29元

1天体验卡首发特惠仅需5.99元

了解详情
不再提醒
插件&应用
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
高级版
套餐订阅购买积分包
AI 工具
文献检索文档翻译深度研究
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2025

基于纳米尺寸分子印迹聚合物-碳糊电极的对羟基苯甲酸丙酯选择性和高灵敏度伏安传感器的研制。

Development of a selective and sensitive voltammetric sensor for propylparaben based on a nanosized molecularly imprinted polymer-carbon paste electrode.

机构信息

Department of Analytical Chemistry, Faculty of Chemistry, Razi University, Kermanshah, Iran.

Department of Analytical Chemistry, Faculty of Chemistry, Razi University, Kermanshah, Iran.

出版信息

Mater Sci Eng C Mater Biol Appl. 2014 Mar 1;36:102-7. doi: 10.1016/j.msec.2013.11.021. Epub 2013 Nov 27.


DOI:10.1016/j.msec.2013.11.021
PMID:24433892
Abstract

The design and construction of a selective voltammetric sensor for propylparaben (PP) in cosmetics by using a molecularly imprinted polymer (MIP) as recognition element was introduced. The MIP was synthesized by using PP as template and methacrylic acid as functional monomer and then incorporated in the carbon paste electrode as PP sensor. The molecularly imprinted polymer-carbon paste electrode (MIP-CPE) showed very high recognition ability in comparison to non-imprinted polymer-carbon paste electrode (NIP-CPE). It was shown that electrode washing after PP extraction, led to enhanced selectivity, without noticeably decreasing the sensitivity. Some parameters affecting sensor response were optimized, and a calibration curve was then plotted using differential pulse voltammetric (DPV) technique. A dynamic linear range of 1 nM to 100 nM was obtained. The detection limit of the sensor was calculated to be equal to 0.32 nM. The imprinted electrode also displayed good selectivity for PP and selectivity coefficients were 2.29 and 1.66 for methylparaben (MP) and ethylparaben (EP) respectively. Structural analogs, such as phenol and p-hydroxybenzoic acid had almost no response. This sensor was used successfully for propylparaben determination in cosmetic sample.

摘要

采用分子印迹聚合物(MIP)作为识别元件,设计并构建了一种用于化妆品中对羟基苯甲酸丙酯(PP)的选择性伏安传感器。该 MIP 以 PP 为模板,甲基丙烯酸为功能单体合成,然后作为 PP 传感器掺入到碳糊电极中。与非印迹聚合物-碳糊电极(NIP-CPE)相比,分子印迹聚合物-碳糊电极(MIP-CPE)具有非常高的识别能力。结果表明,在 PP 提取后进行电极清洗,可提高选择性,而不会明显降低灵敏度。优化了影响传感器响应的一些参数,然后使用差分脉冲伏安法(DPV)技术绘制校准曲线。得到了 1 nM 至 100 nM 的动态线性范围。传感器的检测限计算为 0.32 nM。印迹电极对 PP 也表现出良好的选择性,对甲基对羟基苯甲酸酯(MP)和乙基对羟基苯甲酸酯(EP)的选择性系数分别为 2.29 和 1.66。结构类似物,如苯酚和对羟基苯甲酸几乎没有响应。该传感器成功用于化妆品样品中对羟基苯甲酸丙酯的测定。

相似文献

[1]
Development of a selective and sensitive voltammetric sensor for propylparaben based on a nanosized molecularly imprinted polymer-carbon paste electrode.

Mater Sci Eng C Mater Biol Appl. 2013-11-27

[2]
A novel high selective and sensitive para-nitrophenol voltammetric sensor, based on a molecularly imprinted polymer-carbon paste electrode.

Talanta. 2009-10-15

[3]
Electrochemical sensor for parabens based on molecular imprinting polymers with dual-templates.

Anal Chim Acta. 2010-6-4

[4]
A novel high selective and sensitive metronidazole voltammetric sensor based on a molecularly imprinted polymer-carbon paste electrode.

Talanta. 2011-2-22

[5]
Voltammetric sensor based on carbon paste electrode modified with molecular imprinted polymer for determination of sulfadiazine in milk and human serum.

Mater Sci Eng C Mater Biol Appl. 2013-8-12

[6]
Fabrication of an electrochemical sensor based on computationally designed molecularly imprinted polymers for determination of cyanazine in food samples.

Anal Chim Acta. 2011-11-25

[7]
Graphene/graphite paste electrode incorporated with molecularly imprinted polymer nanoparticles as a novel sensor for differential pulse voltammetry determination of fluoxetine.

Biosens Bioelectron. 2016-2-18

[8]
Novel amperometric flow-injection analysis of creatinine using a molecularly-imprinted polymer coated copper oxide nanoparticle-modified carbon-paste-electrode.

J Pharm Biomed Anal. 2019-7-13

[9]
Molecularly imprinted polymer based electrochemical detection of L-cysteine at carbon paste electrode.

Mater Sci Eng C Mater Biol Appl. 2014-4-1

[10]
Highly selective extraction and voltammetric determination of the opioid drug buprenorphine via a carbon paste electrode impregnated with nano-sized molecularly imprinted polymer.

Mikrochim Acta. 2019-8-28

引用本文的文献

[1]
Dual-Functional Monomer MIPs and Their Comparison to Mono-Functional Monomer MIPs for SPE and as Sensors.

Polymers (Basel). 2022-8-26

[2]
Molecularly imprinted polymeric coatings for sensitive and selective gravimetric detection of artemether.

RSC Adv. 2020-9-16

[3]
Co-precipitation polymerization of dual functional monomers and polystyrene--divinylbenzene for ciprofloxacin imprinted polymer preparation.

RSC Adv. 2021-10-22

[4]
Hydrothermal synthesis of a novel nanolayered tin phosphate for removing Cr(iii).

RSC Adv. 2021-1-22

[5]
Carbon Materials in Electroanalysis of Preservatives: A Review.

Materials (Basel). 2021-12-11

[6]
Critical overview on the application of sensors and biosensors for clinical analysis.

Trends Analyt Chem. 2016-12

[7]
A New Sensor for Methyl Paraben Using an Electrode Made of a Cellulose Nanocrystal-Reduced Graphene Oxide Nanocomposite.

Sensors (Basel). 2019-6-18

[8]
Electrochemical quercetin sensor based on a nanocomposite consisting of magnetized reduced graphene oxide, silver nanoparticles and a molecularly imprinted polymer on a screen-printed electrode.

Mikrochim Acta. 2017-12-20

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

推荐工具

医学文档翻译智能文献检索