Morcillo Sara P, Martínez-Peragón Ángela, Jakoby Verena, Mota Antonio J, Kube Christian, Justicia José, Cuerva Juan M, Gansäuer Andreas
Department of Organic Chemistry, University of Granada, Fuentenueva Campus, Granada 18071, Spain.
Chem Commun (Camb). 2014 Feb 28;50(17):2211-3. doi: 10.1039/c3cc49230c. Epub 2014 Jan 16.
Titanocene carboxylate 1 is an excellent chemoselective reagent for unprecedented α-regioselective Barbier-type reactions. It constitutes the first titanocene(III) able to tolerate epoxides and readily reduced carbonyl compounds, such as aromatic and α,β-unsaturated aldehydes.
羧基二茂钛1是一种出色的化学选择性试剂，可用于前所未有的α-区域选择性巴比耶型反应。它是第一种能够耐受环氧化物以及易还原羰基化合物（如芳香醛和α,β-不饱和醛）的三价二茂钛。
