(+)- 毛蕊花呋喃和 (-)- 安尼索呋喃的合成。
Synthesis of (+)-luzofuran and (-)-ancistrofuran.
机构信息
School of Chemistry, University of Sydney , Sydney 2006, Australia.
出版信息
J Org Chem. 2014 Feb 7;79(3):880-7. doi: 10.1021/jo402790x. Epub 2014 Jan 22.
Abstract
The first synthesis of the furan-containing snyderane, (+)-luzofuran, is reported. The key step in this approach was an electrophilic brominative cyclization, which was accomplished using a nucleophilic N-heterocycle-flanked phosphoramidite catalyst in combination with the common laboratory reagent N-bromosuccinimide.
摘要
首次报道了含呋喃的杉德烷（+）-卢佐呋喃的全合成。该方法的关键步骤是亲电溴化环化，使用亲核 N-杂环侧翼磷酰胺催化剂与常用实验室试剂 N-溴代丁二酰亚胺相结合来完成。
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