State Key Laboratory of Chemical Resource, Engineering & Key Laboratory of Carbon Fiber and Functional Polymer, Ministry of Education, Beijing University of Chemical Technology, 15 Beisanhuan East Road, Chaoyang District, Beijing, 100029, P.R. China.
Adv Mater. 2014 May 21;26(19):3009-13. doi: 10.1002/adma.201305177. Epub 2014 Jan 22.
Macroscopic supramolecular assembly is a promising method for manufacturing macroscopic, ordered structures for tissue-engineering scaffolds. A flexible spacing coating is shown to overcome undesired surface and size effects and to enable assembly of macroscopic cubes with host/guest groups. The assembled pairs disassembled upon introduction of competitive guest molecules, thereby demonstrating a multivalent assembly mechanism.
宏观超分子组装是制造用于组织工程支架的宏观、有序结构的一种很有前途的方法。柔性间隔涂层被证明可以克服不理想的表面和尺寸效应，并能够组装具有主/客体基团的宏观立方体形。组装对在引入竞争客体分子后解组装，从而证明了多价组装机制。
