Department of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universitaet Erlangen-Nuernberg, Egerlandstr. 3, 91058, Erlangen, Germany.
Adv Mater. 2014 Mar 12;26(10):1482-93. doi: 10.1002/adma.201304928. Epub 2014 Feb 14.
The past 25 years have served as a test bed for exploring the chemistry and physics, in general, and the electron transfer chemistry, in particular, of low-dimensional carbon. Nevertheless, the new realm started with the advent of fullerenes, followed in chronological order by carbon nanotubes, and, more recently, by graphene. The major thrust of this Review article is to historically recap the versatility of fullerenes regarding the design, the synthesis, and the tests as an electroactive building block in photosynthetic reaction mimics, photovoltaics, and catalysis.
过去的 25 年是探索化学和物理学的试验田，尤其是低维碳的电子转移化学。然而，这个新领域始于富勒烯的出现，随后按时间顺序出现了碳纳米管，最近又出现了石墨烯。本文的主要目的是回顾富勒烯在光合作用模拟、光伏和催化等电活性构建块的设计、合成和测试方面的多功能性。
