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[细菌的抗原多糖。31. 橙色假单胞菌IMB 31脂多糖O-特异性多糖链的结构]

[Antigenic polysaccharides of bacteria. 31. The structure of the O-specific polysaccharide chain of Pseudomonas aurantiaca IMB 31 lipopolysaccharide].

作者信息

Knirel' Iu A, Zdorovenko G M, Veremeĭchenko S I, Lipkind G M, Shashkova A S

出版信息

Bioorg Khim. 1988 Mar;14(3):352-8.

PMID:2454632
Abstract

The O-specific polysaccharide chain of the Pseudomonas aurantiaca IMV 31 lipopolysaccharide contains N-acetyl-L-fucosamine (FucNAc) and di-N-acetyl-D-bacillosamine (2,4-diacetamido-2,4,6-trideoxyglucose, Bac(NAc)2) in the ratio 2:1. On the basis of methylation, solvolysis with anhydrous hydrogen fluoride, and computer-assisted analysis of 13C-NMR spectrum, it was concluded that the trisaccharide repeating unit of the polysaccharide possesses the following structure: structure: ----3)-beta-D-Bac(NAc)2-(1----3)-alpha-L-FucNAc-(1----3)-alpha-L- FucNAc-(1----.

摘要

橙色假单胞菌IMV 31脂多糖的O-特异性多糖链含有N-乙酰基-L-岩藻糖胺(FucNAc)和二-N-乙酰基-D-芽孢杆菌胺(2,4-二乙酰氨基-2,4,6-三脱氧葡萄糖,Bac(NAc)2),其比例为2:1。基于甲基化、无水氟化氢醇解以及13C-NMR谱的计算机辅助分析,得出该多糖的三糖重复单元具有以下结构:结构:----3)-β-D-Bac(NAc)2-(1----3)-α-L-FucNAc-(1----3)-α-L- FucNAc-(1----。

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