National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan.
J Synchrotron Radiat. 2014 Mar;21(Pt 2):325-32. doi: 10.1107/S1600577513030877. Epub 2014 Jan 31.
The design, construction and commissioning of a beamline and spectrometer for inelastic soft X-ray scattering at high resolution in a highly efficient system are presented. Based on the energy-compensation principle of grating dispersion, the design of the monochromator-spectrometer system greatly enhances the efficiency of measurement of inelastic soft X-rays scattering. Comprising two bendable gratings, the set-up effectively diminishes the defocus and coma aberrations. At commissioning, this system showed results of spin-flip, d-d and charge-transfer excitations of NiO. These results are consistent with published results but exhibit improved spectral resolution and increased efficiency of measurement. The best energy resolution of the set-up in terms of full width at half-maximum is 108 meV at an incident photon energy tuned about the Ni L3-edge.
提出了一种在高效率系统中进行高分辨率非弹性软 X 射线散射的光束线和光谱仪的设计、构建和调试。基于光栅色散的能量补偿原理,单色仪-光谱仪系统的设计极大地提高了非弹性软 X 射线散射测量的效率。该装置由两个可弯曲的光栅组成,有效地减小了离焦和彗差像差。在调试过程中,该系统显示了 NiO 的自旋翻转、d-d 和电荷转移激发的结果。这些结果与已发表的结果一致,但表现出了改进的光谱分辨率和提高的测量效率。该装置在调谐到 Ni L3 边缘附近的入射光子能量时,以半最大值全宽的最佳能量分辨率为 108 meV。