Zhou Ke Jin, Matsuyama Satoshi, Strocov Vladimir N
Diamond Light Source, Harwell Campus, Didcot OX11 0DE, United Kingdom.
Department of Precision Science and Technology, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka, Japan.
J Synchrotron Radiat. 2020 Sep 1;27(Pt 5):1235-1239. doi: 10.1107/S1600577520008607. Epub 2020 Aug 5.
Upon progressive refinement of energy resolution, the conventional resonant inelastic X-ray scattering (RIXS) instrumentation reaches the limit where the bandwidth of incident photons becomes insufficient to deliver an acceptable photon-count rate. Here it is shown that RIXS spectra as a function of energy loss are essentially invariant to their integration over incident energies within the core-hole lifetime. This fact permits RIXS instrumentation based on the hv-concept to utilize incident synchrotron radiation over the whole core-hole lifetime window without any compromise on the much finer energy-loss resolution, thereby breaking the photon-count limit.
随着能量分辨率的逐步提高,传统的共振非弹性X射线散射(RIXS)仪器达到了一个极限,即入射光子的带宽变得不足以提供可接受的光子计数率。本文表明,作为能量损失函数的RIXS光谱在芯孔寿命内对其在入射能量上的积分基本不变。这一事实使得基于hv概念的RIXS仪器能够在整个芯孔寿命窗口内利用入射同步辐射,而不会在精细得多的能量损失分辨率上做出任何妥协,从而突破光子计数限制。