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Regio- and stereoselective 1,2-dihydropyridine alkylation/addition sequence for the synthesis of piperidines with quaternary centers.
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Tantalum catalyzed hydroaminoalkylation for the synthesis of α- and β-substituted N-heterocycles.
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The regio- and stereoselective synthesis of trans-2,3-dihydropyridine N-oxides and piperidines.
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Synthesis of pyridine and dihydropyridine derivatives by regio- and stereoselective addition to N-activated pyridines.
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Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis.
Science. 2013 Feb 8;339(6120):678-82. doi: 10.1126/science.1230704.
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Enantioselective Diels-Alder reaction of 1,2-dihydropyridines with aldehydes using β-amino alcohol organocatalyst.
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2
Substituted Dihydropyridine Synthesis by Dearomatization of Pyridines.
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Controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis.
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π-Facial Selectivities in Hydride Reductions of Hindered Endocyclic Iminium Ions.
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Iridium-catalyzed selective 1,2-hydrosilylation of N-heterocycles.
Chem Sci. 2016 Aug 1;7(8):5362-5370. doi: 10.1039/c6sc01037g. Epub 2016 Apr 26.
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Rh(I)-Catalyzed Cycloisomerization of 1,6-Enynes.
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Synthesis of Ethers via Reaction of Carbanions and Monoperoxyacetals.
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Addition of organometallic reagents to chiral N-methoxylactams: enantioselective syntheses of pyrrolidines and piperidines.
Chemistry. 2013 Dec 2;19(49):16746-55. doi: 10.1002/chem.201302735. Epub 2013 Oct 21.
2
Nickel-catalyzed enantioselective arylation of pyridinium ions: harnessing an iminium ion activation mode.
Angew Chem Int Ed Engl. 2013 Aug 26;52(35):9153-6. doi: 10.1002/anie.201303994. Epub 2013 Jul 10.
4
A catalytic asymmetric synthesis of polysubstituted piperidines using a rhodium(I)-catalyzed [2+2+2] cycloaddition employing a cleavable tether.
Angew Chem Int Ed Engl. 2013 May 10;52(20):5368-71. doi: 10.1002/anie.201301741. Epub 2013 Apr 19.
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Highly enantioselective rhodium-catalyzed [2+2+2] cycloaddition of diynes to sulfonimines.
J Am Chem Soc. 2013 Mar 27;135(12):4576-9. doi: 10.1021/ja309301n. Epub 2013 Mar 13.
7
Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis.
Science. 2013 Feb 8;339(6120):678-82. doi: 10.1126/science.1230704.
9
Annulation of α,β-unsaturated imines and alkynes via cobalt-catalyzed olefinic C-H activation.
Org Lett. 2013 Jan 4;15(1):196-9. doi: 10.1021/ol303259m. Epub 2012 Dec 21.
10
Synthesis of alkaloid (-)-205B via stereoselective reductive cross-coupling and intramolecular [3+2] cycloaddition.
J Am Chem Soc. 2012 Sep 19;134(37):15237-40. doi: 10.1021/ja306362m. Epub 2012 Sep 7.

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