铑(III)催化的芳烃 C-H 活化和酰胺化反应，使用 N-芳基磺酰基酰亚胺作为酰胺化试剂。
Rhodium(III)-catalyzed C-H activation and amidation of arenes using N-arenesulfonated imides as amidating reagents.
机构信息
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
出版信息
Org Lett. 2013 Jul 19;15(14):3706-9. doi: 10.1021/ol401569u. Epub 2013 Jul 3.
PMID:23822068
Abstract
Rhodium(III)-catalyzed C-H activation-amidation of arenes bearing chelating groups has been achieved using N-arenesulfonated imides as efficient amidating reagents without using any base additive. Pyridine, oxime, and pyrimidine proved to be viable directing groups.
摘要
铑(III)催化的芳基螯合基团 C-H 活化-酰胺化反应已经实现，使用 N-芳基磺酰胺基酰亚胺作为高效的酰胺化试剂，无需使用任何碱添加剂。吡啶、肟和嘧啶被证明是可行的导向基团。
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