Institut für Textilchemie und Chemiefasern (ITCF Denkendorf), Körschtalstrasse 26, 73770 Denkendorf (Germany).
Angew Chem Int Ed Engl. 2014 May 19;53(21):5262-98. doi: 10.1002/anie.201306129. Epub 2014 Mar 25.
This Review gives an overview of precursor systems, their processing, and the final precursor-dependent structure of carbon fibers (CFs) including new developments in precursor systems for low-cost CFs. The following CF precursor systems are discussed: poly(acrylonitrile)-based copolymers, pitch, cellulose, lignin, poly(ethylene), and new synthetic polymeric precursors for high-end CFs. In addition, structure-property relationships and the different models for describing both the structure and morphology of CFs will be presented.
这篇综述概述了前体系统、它们的加工以及碳纤维(CF)的最终前体依赖结构,包括低成本 CF 前体系统的新进展。讨论了以下 CF 前体系统:基于聚丙烯腈的共聚物、沥青、纤维素、木质素、聚乙烯和用于高端 CF 的新型合成聚合物前体。此外,还将介绍结构-性能关系以及描述 CF 结构和形态的不同模型。