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Deconstruction of rubber via C-H amination and aza-Cope rearrangement.
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Iterative synthesis of stereodefined polyacetals and their domino-Coates-Claisen rearrangement.
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2
Catalytic enantioselective allylic amination of unactivated terminal olefins via an ene reaction/[2,3]-rearrangement.
J Am Chem Soc. 2012 Nov 14;134(45):18495-8. doi: 10.1021/ja307851b. Epub 2012 Oct 29.
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A gold-catalysed enantioselective Cope rearrangement of achiral 1,5-dienes.
Nat Chem. 2012 Apr 15;4(5):405-9. doi: 10.1038/nchem.1327.
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Generation and rearrangements of oxonium ylides.
J Am Chem Soc. 1986 Sep 1;108(19):6062-3. doi: 10.1021/ja00279a077.
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Intramolecular generation and [2,3]-sigmatropic rearrangement of oxonium ylides.
J Am Chem Soc. 1986 Sep 1;108(19):6060-2. doi: 10.1021/ja00279a076.
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Tandem catalytic allylic amination and [2,3]-Stevens rearrangement of tertiary amines.
J Am Chem Soc. 2011 Aug 24;133(33):12956-9. doi: 10.1021/ja204717b. Epub 2011 Aug 3.
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Cascade polycyclisations in natural product synthesis.
Org Biomol Chem. 2011 Jun 7;9(11):3997-4006. doi: 10.1039/c1ob05212h. Epub 2011 Apr 28.
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Catalytic enantioselective [2,3]-rearrangements of amine N-oxides.
J Am Chem Soc. 2011 Feb 9;133(5):1206-8. doi: 10.1021/ja110500m. Epub 2011 Jan 10.

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