木糖菌素B假定结构的全合成
Total synthesis of the putative structure of xylarinol B.
作者信息
More Atul A, Ramana Chepuri V
机构信息
Division of Organic Chemistry, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune - 411 008 (India), Fax: (+91) 20-25902629.
出版信息
Chem Asian J. 2014 Jun;9(6):1557-62. doi: 10.1002/asia.201301647. Epub 2014 Mar 27.
PMID:24678029
Abstract
The total synthesis of the putative structure of xylarinol B is described and the need to revise its structure is demonstrated. The central benzoxepine skeleton was constructed by employing a cobalt-mediated bimolecular [2+2+2] Reppe-Vollhardt alkyne cycloaddition reaction.
摘要
描述了木拉瑞诺醇B假定结构的全合成，并证明了修正其结构的必要性。通过钴介导的双分子[2+2+2]雷佩-福尔哈特炔烃环加成反应构建了中心苯并氧杂卓骨架。
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