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负载于碳球上的分级结构二硫化钼壳层用于高度可逆的锂存储。

Hierarchical MoS2 shells supported on carbon spheres for highly reversible lithium storage.

作者信息

Zhang Lei, Lou Xiong Wen David

机构信息

School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459 (Singapore), Web: http://www.ntu.edu.sg/home/xwlou/

出版信息

Chemistry. 2014 Apr 25;20(18):5219-23. doi: 10.1002/chem.201400128. Epub 2014 Mar 28.

Abstract

Hierarchical MoS2 shells supported on carbon spheres (denoted as C@MoS2) have been synthesized through a one-step hydrothermal method. The obtained hierarchical C@MoS2 microspheres simultaneously integrate the structural and compositional design rationales for high-energy electrode materials based on two-dimensional (2D) nanosheets. When evaluated as an anode material for lithium-ion batteries (LIBs), the hierarchical C@MoS2 microspheres manifest high specific capacity, enhanced cycling stability and good rate capability.

摘要

通过一步水热法合成了负载在碳球上的分级二硫化钼壳层(表示为C@MoS2)。所获得的分级C@MoS2微球同时整合了基于二维(2D)纳米片的高能电极材料的结构和组成设计原理。当作为锂离子电池(LIBs)的负极材料进行评估时,分级C@MoS2微球表现出高比容量、增强的循环稳定性和良好的倍率性能。

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