College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, China.
Chem Soc Rev. 2014 Aug 21;43(16):5618-56. doi: 10.1039/c4cs00041b.
Metal-organic frameworks (MOFs), also known as porous coordination polymers (PCPs), are an emerging type of porous materials which are formed by the self-assembly of metallic centers and bridging organic linkers. Design and synthesis of organic linkers are very critical to target MOFs with desired structures and properties. In this review, we summarize and highlight the recent development of porous MOFs that are constructed from the multicarboxylate ligands containing m-benzenedicarboxylate moieties, and their promising applications in gas storage and separation, heterogeneous catalysis and luminescent sensing.
金属-有机骨架（MOFs），也称为多孔配位聚合物（PCPs），是一种新兴的多孔材料，由金属中心和桥连有机配体自组装而成。设计和合成有机配体对于目标 MOFs 的结构和性能至关重要。在本文中，我们总结和强调了由含有间苯二甲酸部分的多羧酸配体构建的多孔 MOFs 的最新发展，及其在气体储存和分离、多相催化和发光传感等方面的应用前景。
