National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan.
Chem Soc Rev. 2014 Aug 21;43(16):5468-512. doi: 10.1039/c3cs60472a.
Metal-organic frameworks (MOFs), also known as porous coordination polymers (PCPs), synthesized by assembling metal ions with organic ligands have recently emerged as a new class of crystalline porous materials. The amenability to design as well as fine-tunable and uniform pore structures makes them promising materials for a variety of applications. Controllable integration of MOFs and functional materials is leading to the creation of new multifunctional composites/hybrids, which exhibit new properties that are superior to those of the individual components through the collective behavior of the functional units. This is a rapidly developing interdisciplinary research area. This review provides an overview of the significant advances in the development of diverse MOF composites reported till now with special emphases on the synergistic effects and applications of the composites. The most widely used and successful strategies for composite synthesis are also presented.
金属-有机框架（MOFs），也称为多孔配位聚合物（PCPs），是由金属离子与有机配体组装而成的新型结晶多孔材料。其设计的灵活性以及可精细调节和均匀的孔结构，使它们成为各种应用的有前途的材料。MOFs 与功能材料的可控集成导致了新型多功能复合材料/杂化材料的产生，这些材料通过功能单元的集体行为表现出优于单个组件的新性质。这是一个快速发展的跨学科研究领域。本综述概述了迄今为止报道的各种 MOF 复合材料的重要进展，特别强调了复合材料的协同效应和应用。还介绍了最广泛使用和成功的复合材料合成策略。
