零价铜这种常见金属作为通过控制添加剂制备腈类和亚胺类化合物的高效催化剂。
Common metal of copper(0) as an efficient catalyst for preparation of nitriles and imines by controlling additives.
作者信息
Wang Jiaqing, Lu Shuanglong, Cao Xueqin, Gu Hongwei
机构信息
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, 215123, China.
出版信息
Chem Commun (Camb). 2014 May 30;50(42):5637-40. doi: 10.1039/c4cc01389a.
A novel, efficient, convenient and environmentally friendly approach for the synthesis of nitriles and imines from primary amines has been developed. Using commercially available red copper as the catalyst, ammonium bromide as the co-catalyst and molecular oxygen as the sole oxidant, nitriles and imines can be afforded in high yields through benzylic oxidation.
已经开发出一种新颖、高效、便捷且环保的方法，用于从伯胺合成腈和亚胺。使用市售的红铜作为催化剂，溴化铵作为助催化剂，分子氧作为唯一的氧化剂，通过苄基氧化可以高产率得到腈和亚胺。
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