1] IBM Research Division, Almaden Research Center, 650 Harry Road, San Jose, California 95120-6099, USA [2] Department of Applied Physics, Stanford University, 348 Via Pueblo, Stanford, California 94305, USA.
IBM Research Division, Almaden Research Center, 650 Harry Road, San Jose, California 95120-6099, USA.
Nat Nanotechnol. 2014 Jun;9(6):453-8. doi: 10.1038/nnano.2014.71. Epub 2014 Apr 20.
Strong interactions, or correlations, between the d or f electrons in transition-metal oxides lead to various types of metal-insulator transitions that can be triggered by external parameters such as temperature, pressure, doping, magnetic fields and electric fields. Electric-field-induced metallization of such materials from their insulating states could enable a new class of ultrafast electronic switches and latches. However, significant questions remain about the detailed nature of the switching process. Here, we show, in the canonical metal-to-insulator transition system V₂O₃, that ultrafast voltage pulses result in its metallization only after an incubation time that ranges from ∼150 ps to many nanoseconds, depending on the electric field strength. We show that these incubation times can be accounted for by purely thermal effects and that intrinsic electronic-switching mechanisms may only be revealed using larger electric fields at even shorter timescales.
强相互作用或关联,在过渡金属氧化物的 d 或 f 电子,导致各种类型的金属-绝缘体转变,可以由外部参数,如温度,压力,掺杂,磁场和电场触发。从绝缘状态到金属态的这种材料的电场诱导,可能使超快电子开关和锁存器成为可能。然而,关于开关过程的详细性质,仍存在许多问题。在这里,我们在典型的金属-绝缘体转变系统 V₂O₃中表明,超快电压脉冲仅在孵育时间后导致其金属化,孵育时间范围从约 150 ps 到数纳秒,取决于电场强度。我们表明,这些孵育时间可以用纯粹的热效应来解释,并且只有在甚至更短的时间尺度下使用更大的电场,才能揭示出内在的电子开关机制。