可见光诱导氧化偶联反应：轻松获得曼尼希型产物。
Visible light-induced oxidative coupling reaction: easy access to Mannich-type products.
机构信息
State Key Lab of Urban Water Resource and Environment, The Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin 150080, China.
出版信息
Chem Commun (Camb). 2012 Feb 25;48(17):2337-9. doi: 10.1039/c2cc17130a. Epub 2012 Jan 18.
PMID:22252544
Abstract
An efficient methodology for the functionalization of sp(3) C-H bond adjacent to nitrogen has been developed utilizing visible light-induced photoredox catalysis. Through optimization of solvent and light source, the reaction can be rapidly achieved to provide the desired product under mild reaction conditions.
摘要
本文开发了一种利用可见光诱导光氧化还原催化的 sp(3) C-H 键与氮相邻的官能化的有效方法。通过对溶剂和光源的优化，该反应可以在温和的反应条件下快速进行，以提供所需的产物。
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