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斯德哥尔摩阿兰达机场作为全氟和多氟烷基物质进入水、沉积物和鱼类的来源。

Stockholm Arlanda Airport as a source of per- and polyfluoroalkyl substances to water, sediment and fish.

机构信息

Dept. of Aquatic Sciences and Assessment, Swedish University of Agricultural Sciences (SLU), Box 7050, SE-750 07 Uppsala, Sweden.

IVL Swedish Environmental Research Institute, BOX 21060, SE-100 31 Stockholm, Sweden.

出版信息

Chemosphere. 2015 Jun;129:33-8. doi: 10.1016/j.chemosphere.2014.03.136. Epub 2014 May 10.

Abstract

Fire training facilities are potential sources of per- and polyfluoroalkyl substances (PFASs) to the nearby environment due to the usage of PFAS-containing aqueous fire-fighting foams (AFFFs). The multimedia distribution of perfluoroalkyl carboxylates (PFCAs), perfluoroalkyl sulfonates (PFSAs), perfluorooctanesulfonamide (PFOSA) and 6:2 fluorotelomer sulfonate (FTSA) was investigated near a fire training facility at Stockholm Arlanda Airport in Sweden. The whole body burden of PFASs in European perch (Perca fluviatilis) was 334±80μg absolute and was distributed as follows: Gonad>liver≈muscle>blood>gill. The bioconcentration factor (BCF) and sediment/water partition coefficient (Kd) increased by 0.6-1.7 and 0.2-0.5 log units, respectively, for each additional CF2 moiety for PFCAs and PFSAs. PFAS concentrations in water showed no significant decreasing trend between 2009 and 2013 (p>0.05), which indicates that Stockholm Arlanda Airport may be an important source for long-term contamination of the nearby environment with PFASs.

摘要

由于使用了含有全氟和多氟烷基物质(PFAS)的水基消防泡沫(AFFF),消防训练设施可能成为周边环境中 PFAS 的潜在来源。在瑞典斯德哥尔摩阿兰达机场的一个消防训练设施附近,对全氟烷基羧酸(PFCAs)、全氟烷基磺酸盐(PFAS)、全氟辛烷磺酰胺(PFOSA)和 6:2 氟代烷烃磺酸盐(FTSA)进行了多介质分布研究。欧洲鲈鱼(Perca fluviatilis)体内的 PFAS 总负荷为 334±80μg 绝对,分布如下:性腺>肝脏≈肌肉>血液>鳃。对于 PFCAs 和 PFAS,每个额外的 CF2 部分,生物浓缩因子(BCF)和沉积物/水分配系数(Kd)分别增加了 0.6-1.7 和 0.2-0.5 个对数单位。2009 年至 2013 年间,水中的 PFAS 浓度没有明显的下降趋势(p>0.05),这表明斯德哥尔摩阿兰达机场可能是附近环境中 PFAS 长期污染的重要来源。

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