School of Engineering and Applied Sciences, Harvard University , Cambridge, Massachusetts 02138, United States.
Nano Lett. 2014 Jul 9;14(7):3749-54. doi: 10.1021/nl500602n. Epub 2014 Jun 20.
Graphene is an attractive photoconductive material for optical detection due to its broad absorption spectrum and ultrashort response time. However, it remains a great challenge to achieve high responsivity in graphene detectors because of graphene's weak optical absorption (only 2.3% in the monolayer graphene sheet) and short photocarrier lifetime (<1 ps). Here we show that metallic antenna structures can be designed to simultaneously improve both light absorption and photocarrier collection in graphene detectors. The coupled antennas concentrate free space light into the nanoscale deep-subwavelength antenna gaps, where the graphene light interaction is greatly enhanced as a result of the ultrahigh electric field intensity inside the gap. Meanwhile, the metallic antennas are designed to serve as electrodes that collect the generated photocarriers very efficiently. We also elucidate the mechanism of photoconductive gain in the graphene detectors and demonstrate mid-infrared (mid-IR) antenna-assisted graphene detectors at room temperature with more than 200 times enhancement of responsivity (∼0.4 V/W at λ0 = 4.45 μm) compared to devices without antennas (<2 mV/W).
石墨烯因其宽吸收光谱和超短响应时间,是一种很有吸引力的光导材料,适用于光学检测。然而,由于石墨烯的光吸收较弱(单层石墨烯片仅为 2.3%)和光生载流子寿命较短(<1 ps),要实现石墨烯探测器的高响应度仍然是一个巨大的挑战。在这里,我们表明可以设计金属天线结构来同时提高石墨烯探测器的光吸收和光生载流子收集效率。耦合天线将自由空间光集中到纳米尺度的深亚波长天线间隙中,由于间隙内的超高电场强度,石墨烯的光相互作用大大增强。同时,金属天线被设计为电极,可非常有效地收集产生的光生载流子。我们还阐明了石墨烯探测器中的光电导增益机制,并在室温下展示了基于中红外(mid-IR)天线辅助的石墨烯探测器,与没有天线的器件相比(<2 mV/W),其响应度提高了 200 多倍(在 λ0 = 4.45 μm 时约为 0.4 V/W)。