通过钯催化的 C(sp(2))-H 活化/C-O 形成合成乙氧基二苯并氧杂磷杂环氧化物。
Synthesis of ethoxy dibenzooxaphosphorin oxides through palladium-catalyzed C(sp(2))-H activation/C-O formation.
机构信息
Center for Catalytic Organic Reactions, National Creative Research Laboratory (NCRL), Chuncheon 200-701, Republic of Korea.
Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea.
出版信息
Beilstein J Org Chem. 2014 May 23;10:1220-1227. doi: 10.3762/bjoc.10.120. eCollection 2014.
Abstract
We report an efficient Pd-catalyzed C(sp(2))-H activation/C-O bond formation for the synthesis of ethoxy dibenzooxaphosphorin oxides from 2-(aryl)arylphosphonic acid monoethyl esters under aerobic conditions.
摘要
我们报道了一种高效的 Pd 催化的 C(sp(2))-H 活化/C-O 键形成反应，用于在有氧条件下从 2-(芳基)芳基膦酸单乙酯合成乙氧基二苯并氧杂磷杂环氧化物。
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