铑催化的通过 C-H 活化和磷酰胺及膦酰胺基团导向的环化反应的氧化偶联。
Rhodium-catalyzed oxidative coupling through C-H activation and annulation directed by phosphonamide and phosphinamide groups.
机构信息
Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea.
出版信息
Chem Commun (Camb). 2013 Oct 7;49(77):8671-3. doi: 10.1039/c3cc44995e.
PMID:23949774
Abstract
Rhodium-catalyzed oxidative coupling reactions via C-H activation and annulation directed by phosphonamide and phosphinamide groups were developed under aerobic conditions, which produced benzazaphosphole 1-oxides and phosphaisoquinolin-1-oxides.
摘要
铑催化的通过 C-H 活化和磷酰胺及膦酰胺基团导向的氧化偶联反应在有氧条件下发展起来，生成苯并氮杂磷杂环戊烯 1-氧化物和磷杂异喹啉 1-氧化物。
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