室温下钯催化的卤代烯烃立体保持型 Kumada-Corriu 偶联反应。
Stereoretentive Pd-catalyzed Kumada-Corriu couplings of alkenyl halides at room temperature.
作者信息
Krasovskiy Arkady L, Haley Stephen, Voigtritter Karl, Lipshutz Bruce H
机构信息
The Dow Chemical Company, Core R&D, 1776 Building, E4-A, Midland, Michigan 48674, United States.
出版信息
Org Lett. 2014 Aug 15;16(16):4066-9. doi: 10.1021/ol501535w. Epub 2014 Aug 7.
Abstract
Stereoselective palladium-catalyzed Kumada-Corriu reactions of functionalized alkenyl halides and a variety of Grignard reagents, including those bearing β-hydrogen atoms and sensitive functional groups, can be carried out at room temperature using a new combination of reagents.
摘要
使用一种新的试剂组合，在室温下可以进行功能化卤代烯烃与各种格氏试剂（包括那些带有β-氢原子和敏感官能团的格氏试剂）的立体选择性钯催化库马塔-科里乌反应。
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