NMR crystallography: Applications to inorganic materials.

Current developments of NMR crystallography as well as some recent applications to diamagnetic inorganic solids are presented. First, we illustrate how solid-state NMR data can be used in combination with diffraction data for the determination of the periodic part of the crystal structures, from the space group selection, to the structure determination over the refinement and validation processes. As ss-NMR, contrary to diffraction (powder and single-crystal), is not restricted to periodic boundary conditions, ss-NMR data can be used to further complete the structural description of materials, including studies of local order/disorder, etc. This illustrated through examples, which are shown and discussed in the second part of this review.