Martineau Charlotte
Tectospin, Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles St-Quentin en Yvelines, 45, avenue des Etats-Unis, 78035 Versailles cedex, France.
Solid State Nucl Magn Reson. 2014 Oct-Nov;63-64:1-12. doi: 10.1016/j.ssnmr.2014.07.001. Epub 2014 Jul 30.
Current developments of NMR crystallography as well as some recent applications to diamagnetic inorganic solids are presented. First, we illustrate how solid-state NMR data can be used in combination with diffraction data for the determination of the periodic part of the crystal structures, from the space group selection, to the structure determination over the refinement and validation processes. As ss-NMR, contrary to diffraction (powder and single-crystal), is not restricted to periodic boundary conditions, ss-NMR data can be used to further complete the structural description of materials, including studies of local order/disorder, etc. This illustrated through examples, which are shown and discussed in the second part of this review.
本文介绍了核磁共振晶体学的当前发展以及最近在抗磁性无机固体中的一些应用。首先，我们说明了如何将固态核磁共振数据与衍射数据结合使用，以确定晶体结构的周期性部分，从空间群选择到结构精修和验证过程中的结构确定。由于与衍射（粉末和单晶）不同，固态核磁共振不限于周期性边界条件，因此固态核磁共振数据可用于进一步完善材料的结构描述，包括局部有序/无序等研究。本文第二部分通过实例展示并讨论了这一点。
