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[NiFe]氢化酶的（57）Fe标记模型的合成与振动光谱：镍-铁相互作用的首次直接观测

Synthesis and vibrational spectroscopy of (57)Fe-labeled models of [NiFe] hydrogenase: first direct observation of a nickel-iron interaction.

作者信息

Schilter David, Pelmenschikov Vladimir, Wang Hongxin, Meier Florian, Gee Leland B, Yoda Yoshitaka, Kaupp Martin, Rauchfuss Thomas B, Cramer Stephen P

机构信息

Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA.

出版信息

Chem Commun (Camb). 2014 Nov 14;50(88):13469-72. doi: 10.1039/c4cc04572f.

DOI:10.1039/c4cc04572f
PMID:25237680
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4191989/
Abstract

A new route to iron carbonyls has enabled synthesis of (57)Fe-labeled [NiFe] hydrogenase mimic (OC)3(57)Fe(pdt)Ni(dppe). Its study by nuclear resonance vibrational spectroscopy revealed Ni-(57)Fe vibrations, as confirmed by calculations. The modes are absent for (OC)3(57)Fe(pdt)Ni(dppe), which lacks Ni-(57)Fe bonding, underscoring the utility of the analyses in identifying metal-metal interactions.

摘要

一种制备羰基铁的新方法使得合成（57）Fe标记的[NiFe]氢化酶模拟物（OC）3（57）Fe（pdt）Ni（dppe）成为可能。通过核共振振动光谱对其进行的研究揭示了Ni-（57）Fe振动，计算结果证实了这一点。对于缺乏Ni-（57）Fe键的[(OC)3(57)Fe(pdt)Ni(dppe)]+，这些振动模式不存在，这突出了该分析方法在识别金属-金属相互作用方面的实用性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a56/4251067/111f4c86b46c/c4cc04572f-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a56/4251067/16bd5faab098/c4cc04572f-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a56/4251067/070dd58bc88d/c4cc04572f-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a56/4251067/dc09817de64c/c4cc04572f-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a56/4251067/533f201492e2/c4cc04572f-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a56/4251067/111f4c86b46c/c4cc04572f-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a56/4251067/16bd5faab098/c4cc04572f-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a56/4251067/070dd58bc88d/c4cc04572f-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a56/4251067/dc09817de64c/c4cc04572f-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a56/4251067/533f201492e2/c4cc04572f-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a56/4251067/111f4c86b46c/c4cc04572f-f4.jpg

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本文引用的文献

1
[NiFe] hydrogenases: how close do structural and functional mimics approach the active site?
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Organometallics. 2014 Feb 24;33(4):858-867. doi: 10.1021/om400752a. Epub 2014 Feb 3.
3
A metal-metal bond in the light-induced state of [NiFe] hydrogenases with relevance to hydrogen evolution.在与氢气析出反应相关的 [NiFe]氢化酶的光致激发态中存在一个金属-金属键。
氢化酶及其合成模型：金属氢化物的作用。
Chem Rev. 2016 Aug 10;116(15):8693-749. doi: 10.1021/acs.chemrev.6b00180. Epub 2016 Jun 29.
4
Models of the Ni-L and Ni-SIa States of the [NiFe]-Hydrogenase Active Site.[NiFe] -氢化酶活性位点的Ni - L和Ni - SIa状态模型。
Inorg Chem. 2016 Jan 19;55(2):419-31. doi: 10.1021/acs.inorgchem.5b01662. Epub 2015 Sep 30.
5
Hydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopy.通过核共振振动光谱法观察到的[镍铁]氢化酶中的氢化物桥。
Nat Commun. 2015 Aug 10;6:7890. doi: 10.1038/ncomms8890.
J Am Chem Soc. 2013 Mar 13;135(10):3915-25. doi: 10.1021/ja3115899. Epub 2013 Feb 27.
4
Observation of the Fe-CN and Fe-CO vibrations in the active site of [NiFe] hydrogenase by nuclear resonance vibrational spectroscopy.核共振振动光谱观察 [NiFe]氢化酶活性中心的 Fe-CN 和 Fe-CO 振动。
Angew Chem Int Ed Engl. 2013 Jan 7;52(2):724-8. doi: 10.1002/anie.201204616. Epub 2012 Nov 8.
5
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Inorg Chem. 2012 Nov 5;51(21):11787-97. doi: 10.1021/ic3017276. Epub 2012 Oct 5.
6
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7
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8
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