Huang Quan, Qin Xurong, Li Bijin, Lan Jingbo, Guo Qiang, You Jingsong
Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China.
Chem Commun (Camb). 2014 Nov 18;50(89):13739-41. doi: 10.1039/c4cc06291d.
The Cu-catalysed oxidative C-H/C-H coupling reaction of azoles has been used for the first time to develop polymerisation, which provides an efficient method for the preparation of polybenzodiimidazoles. These polymers exhibit high molecular weights, regioregularity, blue-emitting performance and thermal stability.
唑类的铜催化氧化C-H/C-H偶联反应首次被用于发展聚合反应，这为制备聚苯并二咪唑提供了一种有效方法。这些聚合物具有高分子量、区域规整性、蓝光发射性能和热稳定性。
