Wu Xue-Cheng, Zhao Hua-Feng, Zhang Yong-Xin, Zheng Cheng-Hang, Gao Xiang
State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou, 310027, China.
Environ Geochem Health. 2015 Oct;37(5):915-29. doi: 10.1007/s10653-014-9648-x. Epub 2014 Sep 25.
China owns the world's largest capacity of coal-fired power units. By the end of 2012, the capacity of installed national thermal power has been 819.68 million kilowatts. The latest standard requires that newly built power plants emit SO2 in no more than 100 mg/m(3) and the emission of old ones be lower than 200 mg/m(3) while in some key areas the emission should be controlled under 50 mg/m(3). So by the end of 2012, 90% of the active coal-fired units have been equipped with flue gas desulfurization devices. Among the desulfurization methods adopted, limestone-gypsum wet flue gas desulphurization accounts for 92%, causing the problem of fine droplets in the exhaust gas after defogger, which may even form "gypsum rain." At present, sampling methods are widely used at home and abroad, such as magnesium ion tracer method, modified magnesium ion tracer method and chemical analysis. In addition, some scholars use aerodynamic methods, such as ELPI, to measure the diameter distribution and concentration. The methods mentioned above all have their own demerits, such as the inability to on-line, continuous measurements and the need of prolonged measuring time. Thus, in this paper some potential optical on-line methods are presented, such as Fraunhofer diffraction pattern analysis and wavelength-multiplexed laser extinction. Also brought up are their measuring scope and merits. These methods have already been utilized to measure small liquid droplets and their demonstrations and evaluations are as well stated. Finally, a 3D imaging method based on digital holographic microscope is proposed for in-line measurement of size and concentration of slurry droplets. The feasibility of this method is demonstrated by preliminary experimental investigation.
中国拥有世界上最大容量的燃煤发电机组。截至2012年底,全国火电装机容量已达8.1968亿千瓦。最新标准要求新建电厂二氧化硫排放量不超过100毫克/立方米,老电厂排放量低于200毫克/立方米,而在一些重点地区排放量应控制在50毫克/立方米以下。因此,截至2012年底,90%的现役燃煤机组已配备烟气脱硫装置。在所采用的脱硫方法中,石灰石-石膏湿法烟气脱硫占92%,导致除雾器后废气中出现细液滴问题,甚至可能形成“石膏雨”。目前,国内外广泛采用的采样方法有镁离子示踪法、改进的镁离子示踪法和化学分析法等。此外,一些学者采用空气动力学方法,如ELPI,来测量粒径分布和浓度。上述方法都有各自的缺点,如无法在线连续测量、测量时间长等。因此,本文提出了一些潜在的光学在线方法,如夫琅禾费衍射图样分析和波长复用激光消光法,并介绍了它们的测量范围和优点。这些方法已被用于测量小液滴,并对其进行了演示和评估。最后,提出了一种基于数字全息显微镜的三维成像方法,用于在线测量浆液液滴的尺寸和浓度。初步实验研究证明了该方法的可行性。