• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

KTaO₃、CdS、MoS₂半导体及其二元和三元半导体复合材料的表面性质与光催化活性

Surface properties and photocatalytic activity of KTaO3, CdS, MoS2 semiconductors and their binary and ternary semiconductor composites.

作者信息

Bajorowicz Beata, Cybula Anna, Winiarski Michał J, Klimczuk Tomasz, Zaleska Adriana

机构信息

Department of Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, ul. G. Narutowicza 11/12, Gdansk 80-233, Poland.

Department of Solid State Physics, Faculty of Applied Physics and Mathematics, Gdansk University of Technology, ul. G. Narutowicza 11/12, Gdansk 80-233, Poland.

出版信息

Molecules. 2014 Sep 24;19(9):15339-60. doi: 10.3390/molecules190915339.

DOI:10.3390/molecules190915339
PMID:25255249
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6271989/
Abstract

Single semiconductors such as KTaO3, CdS MoS2 or their precursor solutions were combined to form novel binary and ternary semiconductor nanocomposites by the calcination or by the hydro/solvothermal mixed solutions methods, respectively. The aim of this work was to study the influence of preparation method as well as type and amount of the composite components on the surface properties and photocatalytic activity of the new semiconducting photoactive materials. We presented different binary and ternary combinations of the above semiconductors for phenol and toluene photocatalytic degradation and characterized by X-ray powder diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) specific surface area and porosity. The results showed that loading MoS2 onto CdS as well as loading CdS onto KTaO3 significantly enhanced absorption properties as compared with single semiconductors. The highest photocatalytic activity in phenol degradation reaction under both UV-Vis and visible light irradiation and very good stability in toluene removal was observed for ternary hybrid obtained by calcination of KTaO3, CdS, MoS2 powders at the 10:5:1 molar ratio. Enhanced photoactivity could be related to the two-photon excitation in KTaO3-CdS-MoS2 composite under UV-Vis and/or to additional presence of CdMoO4 working as co-catalyst.

摘要

诸如KTaO3、CdS、MoS2等单一半导体或其前驱体溶液，分别通过煅烧法或水热/溶剂热混合溶液法相结合，形成新型二元和三元半导体纳米复合材料。这项工作的目的是研究制备方法以及复合组分的类型和用量对新型半导体光活性材料的表面性质和光催化活性的影响。我们展示了上述半导体用于苯酚和甲苯光催化降解的不同二元和三元组合，并通过X射线粉末衍射（XRD）、紫外-可见漫反射光谱（DRS）、扫描电子显微镜（SEM）、布鲁诺尔-埃米特-泰勒（BET）比表面积和孔隙率进行了表征。结果表明，与单一半导体相比，在CdS上负载MoS2以及在KTaO3上负载CdS显著增强了吸收性能。对于通过以10:5:1摩尔比煅烧KTaO3、CdS、MoS2粉末得到的三元杂化物，在紫外-可见和可见光照射下苯酚降解反应中观察到最高的光催化活性，并且在甲苯去除方面具有非常好的稳定性。增强的光活性可能与KTaO3-CdS-MoS2复合材料在紫外-可见下的双光子激发和/或作为助催化剂的CdMoO4的额外存在有关。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/a1c2480782bd/molecules-19-15339-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/89a79e58d83f/molecules-19-15339-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/792f34d554f2/molecules-19-15339-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/84eaa878b6ae/molecules-19-15339-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/517b57c87418/molecules-19-15339-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/0c8044120451/molecules-19-15339-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/5ec3ecf74acb/molecules-19-15339-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/22dc3974cd1a/molecules-19-15339-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/ec733267b553/molecules-19-15339-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/f6c914034c03/molecules-19-15339-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/a1c2480782bd/molecules-19-15339-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/89a79e58d83f/molecules-19-15339-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/792f34d554f2/molecules-19-15339-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/84eaa878b6ae/molecules-19-15339-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/517b57c87418/molecules-19-15339-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/0c8044120451/molecules-19-15339-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/5ec3ecf74acb/molecules-19-15339-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/22dc3974cd1a/molecules-19-15339-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/ec733267b553/molecules-19-15339-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/f6c914034c03/molecules-19-15339-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6271989/a1c2480782bd/molecules-19-15339-g010.jpg

相似文献

1
Surface properties and photocatalytic activity of KTaO3, CdS, MoS2 semiconductors and their binary and ternary semiconductor composites.KTaO₃、CdS、MoS₂半导体及其二元和三元半导体复合材料的表面性质与光催化活性
Molecules. 2014 Sep 24;19(9):15339-60. doi: 10.3390/molecules190915339.
2
Preparation of CdS and BiS quantum dots co-decorated perovskite-type KNbO ternary heterostructure with improved visible light photocatalytic activity and stability for phenol degradation.制备 CdS 和 BiS 量子点共修饰钙钛矿型 KNbO 三元异质结，提高可见光光催化活性和稳定性，用于苯酚降解。
Dalton Trans. 2018 Oct 30;47(42):15232-15245. doi: 10.1039/c8dt03094d.
3
Novel α-Fe2O3/CdS cornlike nanorods with enhanced photocatalytic performance.具有增强光催化性能的新型 α-Fe2O3/CdS 玉米状纳米棒。
ACS Appl Mater Interfaces. 2012 Sep 26;4(9):4800-6. doi: 10.1021/am3011516. Epub 2012 Aug 23.
4
Photocatalytic hydrogen production of the CdS/TiO2-WO3 ternary hybrid under visible light irradiation.CdS/TiO₂-WO₃三元杂化物在可见光照射下的光催化产氢
Water Sci Technol. 2016;73(7):1667-72. doi: 10.2166/wst.2015.639.
5
CdS microspheres composed of nanocrystals and their photocatalytic activity.由纳米晶体组成的硫化镉微球及其光催化活性。
J Nanosci Nanotechnol. 2011 Mar;11(3):2090-9. doi: 10.1166/jnn.2011.3760.
6
Synthesis and Visible Photodegradation Enhancement of CdS/mpg-C₃N₄ Photocatalyst.硫化镉/介孔石墨相氮化碳光催化剂的合成及其可见光光降解性能增强
J Nanosci Nanotechnol. 2016 Jan;16(1):471-9. doi: 10.1166/jnn.2016.10661.
7
CdS Nanowires Decorated with Ultrathin MoS2 Nanosheets as an Efficient Photocatalyst for Hydrogen Evolution.用超薄二硫化钼纳米片修饰的硫化镉纳米线作为析氢的高效光催化剂。
ChemSusChem. 2016 Mar 21;9(6):624-30. doi: 10.1002/cssc.201501544. Epub 2016 Feb 16.
8
Developing the Ternary ZnO Doped MoS Nanostructures Grafted on CNT and Reduced Graphene Oxide (RGO) for Photocatalytic Degradation of Aniline.开发接枝在碳纳米管和还原氧化石墨烯（RGO）上的三元氧化锌掺杂二硫化钼纳米结构用于光催化降解苯胺。
Sci Rep. 2020 Mar 10;10(1):4414. doi: 10.1038/s41598-020-61367-7.
9
Electrospun nanofibers of TiO2/CdS heteroarchitectures with enhanced photocatalytic activity by visible light.TiO2/CdS 异质结构的静电纺纳米纤维，可见光下光催化活性增强。
J Colloid Interface Sci. 2011 Jul 1;359(1):220-7. doi: 10.1016/j.jcis.2011.03.044. Epub 2011 Mar 15.
10
Temperature-assisted photochemical construction of CdS-based ordered porous films with photocatalytic activities on solution surfaces.温度辅助的基于 CdS 的有序多孔薄膜的光化学构建及其在溶液表面的光催化活性。
J Colloid Interface Sci. 2011 Apr 15;356(2):783-9. doi: 10.1016/j.jcis.2011.01.027. Epub 2011 Jan 20.

引用本文的文献

1
Structural, electronic, optical and photocatalytic properties of KTaO with NiO cocatalyst modification.具有NiO助催化剂改性的KTaO的结构、电子、光学和光催化性能
RSC Adv. 2022 Nov 10;12(50):32270-32279. doi: 10.1039/d2ra06425a. eCollection 2022 Nov 9.
2
A hydrothermally synthesized MoSSe alloy with deep-shallow level conversion for enhanced performance of photodetectors.一种水热合成的具有深浅能级转换功能的MoSSe合金，用于增强光电探测器的性能。
Nanoscale Adv. 2020 Apr 6;2(5):2185-2191. doi: 10.1039/d0na00202j. eCollection 2020 May 19.
3
Novel 3D-flower shaped KTaO perovskite for highly efficient photocatalytic and H generation ability.

本文引用的文献

1
Synthesis of MoS and MoO for their applications in H generation and lithium ion batteries: a review.用于氢气生成和锂离子电池的二硫化钼和三氧化钼的合成：综述
Sci Technol Adv Mater. 2013 Jul 23;14(4):043501. doi: 10.1088/1468-6996/14/4/043501. eCollection 2013 Aug.
2
Semiconductor Photocatalysis - Past, Present, and Future Outlook.半导体光催化——过去、现在与未来展望
J Phys Chem Lett. 2012 Mar 1;3(5):673-7. doi: 10.1021/jz300071j.
3
Nanochemistry-derived Bi2WO6 nanostructures: towards production of sustainable chemicals and fuels induced by visible light.
新型 3D 花状 KTaO 钙钛矿具有高效光催化和 H2 生成能力。
Sci Rep. 2022 Jun 24;12(1):10776. doi: 10.1038/s41598-022-14590-3.
基于纳米化学的 Bi2WO6 纳米结构：可见光诱导可持续化学品和燃料的生产。
Chem Soc Rev. 2014 Aug 7;43(15):5276-87. doi: 10.1039/c4cs00056k.
4
Selective photoredox using graphene-based composite photocatalysts.基于石墨烯的复合光催化剂的选择性光还原。
Phys Chem Chem Phys. 2013 Nov 28;15(44):19102-18. doi: 10.1039/c3cp53325e.
5
Defective TiO2 with oxygen vacancies: synthesis, properties and photocatalytic applications.具有氧空位的缺陷 TiO2：合成、性质及光催化应用。
Nanoscale. 2013 May 7;5(9):3601-14. doi: 10.1039/c3nr00476g. Epub 2013 Mar 26.
6
On the way to the creation of next generation photoactive materials.在创造下一代光活性材料的道路上。
Environ Sci Pollut Res Int. 2012 Nov;19(9):3666-75. doi: 10.1007/s11356-011-0665-3. Epub 2012 Oct 3.
7
Recent progress on graphene-based photocatalysts: current status and future perspectives.基于石墨烯的光催化剂的最新进展：现状与展望。
Nanoscale. 2012 Sep 28;4(19):5792-813. doi: 10.1039/c2nr31480k. Epub 2012 Aug 20.
8
Recent progress on metal core@semiconductor shell nanocomposites as a promising type of photocatalyst.金属核@半导体壳纳米复合材料作为一种有前途的光催化剂的最新进展。
Nanoscale. 2012 Apr 7;4(7):2227-38. doi: 10.1039/c2nr00009a. Epub 2012 Feb 24.
9
Nano-photocatalytic materials: possibilities and challenges.纳米光催化材料：可能性与挑战。
Adv Mater. 2012 Jan 10;24(2):229-51. doi: 10.1002/adma.201102752. Epub 2011 Oct 4.
10
Morphology driven ultraviolet photosensitivity in ZnO-CdS composite.形态驱动的 ZnO-CdS 复合材料紫外光敏性。
J Colloid Interface Sci. 2011 Dec 1;364(1):10-7. doi: 10.1016/j.jcis.2011.08.001. Epub 2011 Aug 22.