Zhao Yufei, Zhang Yuxia, Yang Zhiyu, Yan Yiming, Sun Kening
School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, People's Republic of China.
Sci Technol Adv Mater. 2013 Jul 23;14(4):043501. doi: 10.1088/1468-6996/14/4/043501. eCollection 2013 Aug.
Scientists increasingly witness the applications of MoS and MoO in the field of energy conversion and energy storage. On the one hand, MoS and MoO have been widely utilized as promising catalysts for electrocatalytic or photocatalytic hydrogen evolution in aqueous solution. On the other hand, MoS and MoO have also been verified as efficient electrode material for lithium ion batteries. In this review, the synthesis, structure and properties of MoS and MoO are briefly summarized according to their applications for H generation and lithium ion batteries. Firstly, we overview the recent advancements in the morphology control of MoS and MoO and their applications as electrocatalysts for hydrogen evolution reactions. Secondly, we focus on the photo-induced water splitting for H generation, in which MoS acts as an important co-catalyst when combined with other semiconductor catalysts. The newly reported research results of the significant functions of MoS nanocomposites in photo-induced water splitting are presented. Thirdly, we introduce the advantages of MoS and MoO for their enhanced cyclic performance and high capacity as electrode materials of lithium ion batteries. Recent key achievements in MoS- and MoO-based lithium ion batteries are highlighted. Finally, we discuss the future scope and the important challenges emerging from these fascinating materials.
科学家们越来越多地见证了二硫化钼(MoS)和三氧化钼(MoO)在能量转换和能量存储领域的应用。一方面,MoS和MoO已被广泛用作在水溶液中进行电催化或光催化析氢的有前景的催化剂。另一方面,MoS和MoO也已被证实是锂离子电池的高效电极材料。在这篇综述中,根据MoS和MoO在制氢及锂离子电池方面的应用,简要总结了它们的合成、结构和性质。首先,我们概述了MoS和MoO形态控制方面的最新进展及其作为析氢反应电催化剂的应用。其次,我们重点关注用于制氢的光致水分解,其中MoS与其他半导体催化剂结合时作为重要的助催化剂。介绍了MoS纳米复合材料在光致水分解中的重要功能的最新报道研究成果。第三,我们介绍了MoS和MoO作为锂离子电池电极材料在增强循环性能和高容量方面的优势。突出了基于MoS和MoO的锂离子电池的近期关键成就。最后,我们讨论了这些迷人材料的未来发展范围以及出现的重要挑战。