用于金属有机框架中长程磁序的配体设计
Ligand design for long-range magnetic order in metal-organic frameworks.
作者信息
Tiana Davide, Hendon Christopher H, Walsh Aron
机构信息
Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK.
出版信息
Chem Commun (Camb). 2014 Nov 21;50(90):13990-3. doi: 10.1039/c4cc06433j.
PMID:25266671
Abstract
We report a class of ligands that are candidates to construct metal-organic frameworks with long-range magnetic order between transition metal centres. Direct quantum chemical calculations predict Néel temperatures exceeding 100 K for the case of Mn.
摘要
我们报道了一类配体，它们有望构建在过渡金属中心之间具有长程磁序的金属有机框架。直接量子化学计算预测，对于锰的情况，奈尔温度超过100K。
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