钯催化酰胺与芳基过氧酰化物的高效脱羧邻位芳基化反应。
A highly efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides.
作者信息
Li Dengke, Xu Ning, Zhang Yicheng, Wang Lei
机构信息
Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China.
出版信息
Chem Commun (Camb). 2014 Dec 7;50(94):14862-5. doi: 10.1039/c4cc06457g.
PMID:25322684
Abstract
An efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides was developed. A variety of anilides reacted with aryl acylperoxides to afford the corresponding ortho-arylation products, and N-methoxyarylamides generated phenanthridinones.
摘要
开发了一种高效的钯催化酰胺与芳基过氧酰化物的脱羧邻位芳基化反应。多种苯胺与芳基过氧酰化物反应，得到相应的邻位芳基化产物，而N-甲氧基芳基酰胺生成菲啶酮。
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