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高功能化 C60 富勒烯衍生物的合成及其在材料和生命科学中的应用。

Synthesis of highly functionalized C60 fullerene derivatives and their applications in material and life sciences.

机构信息

Institute of Organic Chemistry, KIT-Campus South. Fritz-Haber Weg 6, 76131 Karlsruhe, Germany.

出版信息

Org Biomol Chem. 2015 Jan 7;13(1):25-54. doi: 10.1039/c4ob01663g.

Abstract

Highly functionalized fullerenes can be efficiently constructed by various techniques. However, the challenge is to synthesize highly symmetrical fullerenes. Recently, a number of X-ray structures have been disclosed showing the high symmetry of substituted fullerenes. By reviewing the major types of multi functionalized fullerenes through selected examples with a link to the structural assignments, the authors intend to give a concise overview to the specialist in the field and to provide the non-specialist with a tool box of possibilities.

摘要

高度官能化的富勒烯可以通过各种技术有效地构建。然而,挑战在于合成高度对称的富勒烯。最近,已经披露了许多 X 射线结构,显示了取代富勒烯的高对称性。通过回顾通过与结构分配相关的选定示例的主要类型的多功能富勒烯,作者旨在为该领域的专家提供简明概述,并为非专家提供可能性的工具箱。

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