Centre de recherche sur les matériaux lignocellulosiques, Université du Québec à Trois-Rivières, Trois-Rivières, QC G9A 5H7, Canada; PROTEO, Université Laval, Québec, QC G1V 4G2, Canada.
Centre de recherche sur les matériaux lignocellulosiques, Université du Québec à Trois-Rivières, Trois-Rivières, QC G9A 5H7, Canada; Buckman North America, Vaudreuil-Dorion, QC J7V 5V5, Canada.
Carbohydr Polym. 2015 Jan 22;115:193-9. doi: 10.1016/j.carbpol.2014.08.076. Epub 2014 Sep 2.
The importance of enzymes as biotechnological catalysts for paper industry is now recognized. In this study, five cellulase formulations were used for fibre modification. The number of PFI revolutions decreased by about 50% while achieving the same freeness value (decrease in CSF by 200 mL) with the enzymatic pretreatment. The physical properties of handsheets were modified after enzymatic pretreatment followed by PFI refining. A slight decrease in tear strength was observed with enzymes C1 and C4 at pH 7 while the most decrease in tear was observed after C2, C3, C5 treatments. C1 and C4 which had xylanase activity improved paper properties, while other enzymes had a negative impact. Therefore, the intricate balance between cellulolytic and hemicellulolytic activity is the key to optimizing biorefining and paper properties. It was also observed that C1 impact was pH dependent, which supports the importance of pH in developing an enzymatic strategy for refining energy reduction.
酶作为生物技术催化剂在造纸工业中的重要性现在已经得到认可。在这项研究中,使用了五种纤维素酶制剂来进行纤维改性。通过酶预处理,可以在达到相同游离度值(CSF 降低 200mL)的情况下,减少 PFI 打浆的转数约 50%。在进行 PFI 精磨之前进行酶预处理可以改变手抄片的物理性能。在 pH 值为 7 时,酶 C1 和 C4 处理会稍微降低撕裂强度,而在 C2、C3 和 C5 处理后,撕裂强度下降最明显。具有木聚糖酶活性的 C1 和 C4 改善了纸张性能,而其他酶则产生了负面影响。因此,优化生物精炼和纸张性能的关键是保持纤维素酶和半纤维素酶活性之间的精细平衡。还观察到 C1 的影响取决于 pH 值,这支持了在开发用于降低能耗的酶精炼策略时 pH 值的重要性。