Static and dynamic flow analysis of PBDEs in plastics from used and end-of-life TVs and computer monitors by life cycle in Korea.

This study focused on a quantitative substance flow analysis (SFA) of polybrominated diphenyl ethers (PBDEs) in plastics from obsolete TVs and computer monitors that often contain large amounts of the flame retardants. According to the results of the static SFA study, 1.87 tons and 0.28 tons of PBDEs from newly manufactured TVs and computer monitors were introduced into households in 2011 in Korea, respectively. There were approximately 924 tons and 90.3 tons of PBDEs present in TVs and computer monitors in households during product use, respectively. The results of the dynamic SFA study indicated that in 2017 the amount of PBDEs from TVs and computer monitors in the recycling stage is expected to be 2.63 tons and 0.1 tons, respectively. Large fractions of PBDEs from used TVs are present in recycled plastics, while PBDE-containing computer monitors are exported to Southeast Asian countries. This research indicates that PBDEs were emitted the most from recycled plastic pellet processes upon recycling. Further study may be warranted to focus the flow of PBDEs in recycled plastic products in order to determine the final destination and disposal of these chemicals in the environment.