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一种基于萘酰亚胺衍生物的含吡啶的Cu²⁺选择性探针。

A pyridine-containing Cu²⁺-selective probe based on naphthalimide derivative.

作者信息

Zhang Jun, Wu Qiang, Yu Bangliang, Yu Chunwei

机构信息

Laboratory of Environmental Monitoring, School of Tropical and Laboratory Medicine, Hainan Medical University, Haikou 571101, China.

Faculty of Laboratory Medicine, School of Tropical and Laboratory Medicine, Hainan Medical University, Haikou 571101, China.

出版信息

Sensors (Basel). 2014 Dec 15;14(12):24146-55. doi: 10.3390/s141224146.

DOI:10.3390/s141224146
PMID:25517693
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4299103/
Abstract

A new fluorescent probe P derived from naphthalimide bearing a pyridine group has been synthesized and characterized. The proposed probe P shows high selectivity and sensitivity to Cu2+ in aqueous media. Under optimized conditions, the linear response of P (2 μM) toward Cu2+ was 0.05-0.9 μM in ethanol-water solution (3:2, v:v, 50 mM HEPES, pH 7.4), and the detection limit was 0.03 μM.

摘要

一种新的源自带有吡啶基团的萘二甲酰亚胺的荧光探针P已被合成并表征。所提出的探针P在水性介质中对Cu2+表现出高选择性和高灵敏度。在优化条件下，P（2 μM）在乙醇 - 水溶液（3:2，v:v，50 mM HEPES，pH 7.4）中对Cu2+的线性响应为0.05 - 0.9 μM，检测限为0.03 μM。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/5956140decef/sensors-14-24146f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/4929be3e8e3c/sensors-14-24146f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/664b62bfde4f/sensors-14-24146f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/cf1812cc5304/sensors-14-24146f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/42b71692d182/sensors-14-24146f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/9d213339008d/sensors-14-24146f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/5d8c40e35c32/sensors-14-24146f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/067cd0994e02/sensors-14-24146f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/5956140decef/sensors-14-24146f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/4929be3e8e3c/sensors-14-24146f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/664b62bfde4f/sensors-14-24146f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/cf1812cc5304/sensors-14-24146f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/42b71692d182/sensors-14-24146f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/9d213339008d/sensors-14-24146f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/5d8c40e35c32/sensors-14-24146f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/067cd0994e02/sensors-14-24146f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e2e/4299103/5956140decef/sensors-14-24146f8.jpg

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