Liu Zhenqi, Zhong Xiaoxing, Zhang Qi, Lu Caiyuan
Key Laboratory of Gas and Fire Control for Coal Mines (China University of Mining and Technology), Ministry of Education, Xuzhou, 221116, China; School of Safety Engineering, China University of Mining and Technology, Xuzhou, China.
Key Laboratory of Gas and Fire Control for Coal Mines (China University of Mining and Technology), Ministry of Education, Xuzhou, 221116, China; School of Safety Engineering, China University of Mining and Technology, Xuzhou, China.
J Hazard Mater. 2020 Jul 15;394:122561. doi: 10.1016/j.jhazmat.2020.122561. Epub 2020 Mar 19.
To understand the suppression effects of different potassium compounds on methane/air explosions, a 20-L spherical explosion system and a high-speed camera were used to obtain the explosion overpressure and the flame morphology for explosions at different methane concentrations under the action of solutions of five potassium compounds (for the same experimental conditions). The effects of the different additives on the maximum explosion overpressure P, the maximum rate of increase in the overpressure (dp/dt), the time to reach the maximum overpressure t, the deflagration index K and the flame morphology were compared and analyzed. The results indicate that the potassium compounds possessed a relatively strong capability to suppress explosions of nonstoichiometric methane mixtures. Compared with the stoichiometric condition, in 7.5 % and 11.5 % methane/air explosions, there were substantial decreases in P, (dp/dt), and K under the action of the same potassium compounds, meanwhile, t increased considerably, and the maximum overpressure reduction rate reached 20.6 %. Of the five potassium compounds, potassium oxalate had the strongest suppression ability. The strength of the suppression effect by the potassium compounds on the methane/air explosions increased in the following order: potassium dihydrogen phosphate < potassium chloride < potassium acetate < potassium carbonate < potassium oxalate.