Cao Xing-Yan, Bi Ming-Shu, Ren Jing-Jie, Chen Biao
Hefei General Machinery Research Institute Co., Ltd., National Engineering & Technical Research Center on Pressure Vessels and Piping Safety, Hefei, 230031, China.
School of Chemical Machinery and Safety Engineering, Dalian University of Technology, No. 2 Linggong Road, Ganjingzi District, Dalian, 116024, China.
J Hazard Mater. 2019 Apr 15;368:613-620. doi: 10.1016/j.jhazmat.2019.01.006. Epub 2019 Jan 30.
The suppression effects of pure ultrafine water mist and 5% mass fraction alkali metal (NaCl, NaCO, KHCO, KCl and KCO) solutions ultrafine water mist on methane explosion were conducted under five mist concentrations in a sealed visual vessel. Mist diameters of different additive solutions were measured by a phase doppler particle analyzer. Pressure data and dynamic flame pictures were recorded respectively by a high-frequency pressure sensor and a high-speed camera. Results indicate that alkali metal compound can enhance the suppression effect of ultrafine water mist and it was related to the additive type. The suppression order of alkali metal compound for methane explosion was KCO>KCl > KHCO>NaCO>NaCl. Meanwhile, additive radicals can obviously affect explosion intensity and it mainly reflected in the reduction of explosion pressure under different mist conditions (K>Na, Cl >HCO). The pressure generated from combustion wave accelerating propagation underwent two accelerating rises and was affected by additive type and mist amount. The effect of additive type on explosion intensity (maximum explosion overpressure (ΔP), two peak values of pressure rising rate) was similar with flame propagation velocity and were decreased evidently with increasing mist concentration. The enhancement in explosion suppression was due to the combination of improved physical and chemical effects.
在密封可视容器中,于五种雾浓度条件下,研究了纯超细水雾以及质量分数为5%的碱金属(氯化钠、碳酸钠、碳酸氢钾、氯化钾和碳酸钾)溶液超细水雾对甲烷爆炸的抑制效果。采用相位多普勒粒子分析仪测量不同添加剂溶液的雾滴直径。分别通过高频压力传感器和高速摄像机记录压力数据和动态火焰图像。结果表明,碱金属化合物可增强超细水雾的抑制效果,且与添加剂类型有关。碱金属化合物对甲烷爆炸的抑制顺序为碳酸钾>氯化钾>碳酸氢钾>碳酸钠>氯化钠。同时,添加剂基团可明显影响爆炸强度,这主要体现在不同雾条件下爆炸压力的降低(钾>钠,氯>碳酸氢根)。燃烧波加速传播产生的压力经历两次加速上升,且受添加剂类型和雾量的影响。添加剂类型对爆炸强度(最大爆炸超压(ΔP)、压力上升速率的两个峰值)的影响与火焰传播速度相似,且随雾浓度增加而明显降低。爆炸抑制效果的增强归因于物理和化学作用的改善相结合。