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可控折叠石墨烯:GraFold 打印。

Controlled folding of graphene: GraFold printing.

机构信息

Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN) and Advanced Materials BioEngineering Research Centre (AMBER), and ∇School of Chemistry, Trinity College , Dublin 2, Ireland.

出版信息

Nano Lett. 2015 Feb 11;15(2):857-63. doi: 10.1021/nl503460p. Epub 2015 Jan 9.

DOI:10.1021/nl503460p
PMID:25539448
Abstract

We have used elastomeric stamps with periodically varying adhesive properties to introduce structure and print folded graphene films. The structure of the induced folds is investigated with scanning probe techniques, high-resolution electron-microscopy, and tip-enhanced Raman spectroscopy. Furthermore, a finite element model is developed to show the fold formation process. Terahertz spectroscopy reveals induced anisotropy of carrier mobility along, and perpendicular to, the graphene folds. Graphene fold printing is a new technique which allows for significant modification of the properties of 2D materials without damaging or chemically modifying them.

摘要

我们使用具有周期性变化的黏附特性的弹性印章来引入结构并打印折叠的石墨烯薄膜。使用扫描探针技术、高分辨率电子显微镜和尖端增强拉曼光谱研究了所诱导褶皱的结构。此外,还开发了有限元模型来显示褶皱形成过程。太赫兹光谱揭示了沿石墨烯褶皱和垂直于石墨烯褶皱的载流子迁移率的诱导各向异性。石墨烯褶皱打印是一种新技术,它可以在不损坏或化学修饰二维材料的情况下显著改变它们的性质。

相似文献

1
Controlled folding of graphene: GraFold printing.可控折叠石墨烯:GraFold 打印。
Nano Lett. 2015 Feb 11;15(2):857-63. doi: 10.1021/nl503460p. Epub 2015 Jan 9.
2
Mechanical properties of grafold: a demonstration of strengthened graphene.格拉福得力学性能:强化石墨烯的演示。
Nanotechnology. 2011 Oct 7;22(40):405701. doi: 10.1088/0957-4484/22/40/405701. Epub 2011 Sep 7.
3
Nanomechanics of few-layer materials: do individual layers slide upon folding?少层材料的纳米力学:折叠时各层会滑动吗?
Beilstein J Nanotechnol. 2020 Nov 30;11:1801-1808. doi: 10.3762/bjnano.11.162. eCollection 2020.
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Chemically Conjugated Carbon Nanotubes and Graphene for Carrier Modulation.用于载体调控的化学共轭碳纳米管和石墨烯
Acc Chem Res. 2016 Mar 15;49(3):390-9. doi: 10.1021/acs.accounts.5b00441. Epub 2016 Feb 15.
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Fabrication of graphene-based flexible devices utilizing a soft lithographic patterning method.利用软光刻图案化方法制备基于石墨烯的柔性器件。
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Graphene films with large domain size by a two-step chemical vapor deposition process.通过两步化学气相沉积工艺制备具有大畴尺寸的石墨烯薄膜。
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Folding Large Graphene-on-Polymer Films Yields Laminated Composites with Enhanced Mechanical Performance.折叠大尺寸的聚合物/石墨烯复合薄膜可获得具有增强机械性能的层状复合材料。
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Trends in imprint lithography for biological applications.用于生物应用的压印光刻技术的发展趋势。
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引用本文的文献

1
Superlattice in collapsed graphene wrinkles.塌陷石墨烯褶皱中的超晶格。
Sci Rep. 2019 Jul 10;9(1):9972. doi: 10.1038/s41598-019-46372-9.
2
Mastering the Wrinkling of Self-supported Graphene.掌握自支撑石墨烯的起皱。
Sci Rep. 2017 Aug 30;7(1):10003. doi: 10.1038/s41598-017-10153-z.
3
Preparing local strain patterns in graphene by atomic force microscope based indentation.通过原子力显微镜压痕法制备石墨烯中的局域应变图案。
Sci Rep. 2017 Jun 8;7(1):3035. doi: 10.1038/s41598-017-03332-5.