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硅烷偶联剂对微纤化纤维素复合材料力学性能的影响。

Effect of a silane coupling agent on the mechanical properties of a microfibrillated cellulose composite.

作者信息

Ifuku Shinsuke, Yano Hiroyuki

机构信息

Department of Chemistry and Biotechnology, Tottori University, Tottori 680-8502, Japan.

Research Institute for Sustainable Humanosphere, Kyoto University, Uji 611-0011, Japan.

出版信息

Int J Biol Macromol. 2015 Mar;74:428-32. doi: 10.1016/j.ijbiomac.2014.12.029. Epub 2015 Jan 6.

Abstract

Composite materials reinforced with microfibrillated cellulose (MFC) fibers were prepared and characterized in terms of their mechanical properties. The surface of the MFC fibers was treated with a silane coupling reagent having an NH2 functional group to improve fiber-matrix adhesion. Due to the unique structure of the MFC, which consists of nano-order-scale interconnected fibrils and microfibrils with greatly expanded surface area and submicron pore size compared to conventional cellulose, it was possible to enhance the effect of silane coupling agent and thereby improve the compatibility between the fibers and matrix and also the dispersibility of fibers. The Young's modulus was significantly increased to more than 70%.

摘要

制备了用微纤化纤维素(MFC)纤维增强的复合材料,并对其力学性能进行了表征。用具有NH2官能团的硅烷偶联剂处理MFC纤维的表面,以改善纤维与基体的粘附力。由于MFC的独特结构,它由纳米级相互连接的原纤维和微纤维组成,与传统纤维素相比,其表面积大大增加,亚微米孔径增大,因此可以增强硅烷偶联剂的效果,从而提高纤维与基体之间的相容性以及纤维的分散性。杨氏模量显著提高了70%以上。

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